نتريد الزركونيوم
| الأسماء | |
|---|---|
| اسم أيوپاك
Zirconium nitride
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| أسماء أخرى
Zirconium(III) nitride, Nitridozirconium
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| المُعرِّفات | |
| رقم CAS | |
3D model (JSmol)
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| ChEBI | |
| ChemSpider | |
| ECHA InfoCard | 100.042.864 |
| رقم EC |
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PubChem CID
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CompTox Dashboard (EPA)
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| الخصائص | |
| الصيغة الجزيئية | ZrN[1] |
| المظهر | Yellow-brown crystals |
| الرائحة | Odorless |
| الكثافة | 7.09 g/cm3 (24 °C)[1] |
| نقطة الانصهار | |
| قابلية الذوبان في الماء | Insoluble |
| قابلية الذوبان | Soluble in concentrated HF, acids[1] |
| البنية | |
| البنية البلورية | Cubic, cF8[2] |
| الزمرة الفراغية | Fm3m, No. 225[2] |
| ثابت العقد | a = 4.5675 Å[2] |
| ثابت العقد | α = 90°, β = 90°, γ = 90° |
| Octahedral[2] | |
| الكيمياء الحرارية | |
| الإنتالپية المعيارية للتشكل ΔfH |
−365.26 kJ/mol[3] |
| Standard molar entropy S |
38.83 J/(mol·K)[3] |
| سعة الحرارة النوعية، C | 40.442 J/(mol·K)[3] |
| مركبات ذا علاقة | |
refractory ceramic materials ذات العلاقة
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Tantalum carbide Niobium carbide Zirconium carbide |
ما لم يُذكر غير ذلك، البيانات المعطاة للمواد في حالاتهم العيارية (عند 25 °س [77 °ف]، 100 kPa). | |
| مراجع الجدول | |
Zirconium nitride (ZrN) is an inorganic compound used in a variety of ways due to its properties.
Properties
ZrN grown by physical vapor deposition (PVD) is a light gold color similar to elemental gold. ZrN has a room-temperature electrical resistivity of 12.0 μΩ·cm, a temperature coefficient of resistivity of 5.6·10−8 Ω·cm/K, a superconducting transition temperature of 10.4 K, and a relaxed lattice parameter of 0.4575 nm. The hardness of single-crystal ZrN is 22.7±1.7 GPa and elastic modulus is 450 GPa.[4]
Uses
Zirconium nitride is a hard ceramic material similar to titanium nitride and is a cement-like refractory material. Thus it is used in cermets and laboratory crucibles. When applied using the physical vapor deposition coating process it is commonly used for coating medical devices,[5] industrial parts (notably drill bits), automotive and aerospace components and other parts subject to high wear and corrosive environments.
Zirconium nitride was suggested as a hydrogen peroxide fuel tank liner for rockets and aircraft.[6]
References
- ^ أ ب ت قالب:CRC90
- ^ أ ب ت ث Sirajuddeen, M. Md. Sheik.; Banu, I. B. S. (2014). "FP-LAPW investigation of electronic, magnetic, elastic and thermal properties of Fe-doped zirconium nitride". AIP Advances. 4 (5): 057121. Bibcode:2014AIPA....4e7121S. doi:10.1063/1.4879798.
- ^ أ ب ت قالب:Nist
- ^ Mei, A. B.; Howe, B. M.; Zhang, C.; Sardela, M.; Eckstein, J. N.; Hultman, L.; Rockett, A.; Petrov, I.; Greene, J. E. (2013). "Physical properties of epitaxial ZrN/MgO(001) layers grown by reactive magnetron sputtering". Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. 31 (6): 061516. Bibcode:2013JVSTA..31f1516M. doi:10.1116/1.4825349.
- ^ Slate, A. J.; Wickens, D. J.; El Mohtadi, M.; Dempsey-Hibbert, N.; West, G.; Banks, C. E.; Whitehead, K. A. (2018). "Slate, A.J., Wickens, D.J., El Mohtadi, M. et al. Antimicrobial activity of Ti-ZrN/Ag coatings for use in biomaterial applications. Sci Rep 8, 1497 (2018)". Scientific Reports. 8 (1): 1497. doi:10.1038/s41598-018-20013-z. PMC 5784091. PMID 29367635.
- ^ {{{1}}} patent {{{2}}}
| الأملاح والمشتقات المكافئة لأيون النيتريد | |||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| NH3 | He(N2)11 | ||||||||||||||||||
| Li3N | Be3N2 | BN | β-C3N4 g-C3N4 |
N2 | NxOy | NF3 | Ne | ||||||||||||
| Na3N | Mg3N2 | AlN | SiN | PN P3N5 |
SxNy SN S4N4 |
NCl3 | Ar | ||||||||||||
| K3N | Ca3N2 | ScN | TiN | VN | CrN Cr2N |
MnxNy | FexNy | CoN | Ni3N | CuN | Zn3N2 | GaN | Ge3N4 | As | Se | NBr3 | Kr | ||
| Rb3N | Sr3N2 | YN | ZrN | NbN | β-Mo2N | Tc | Ru | Rh | PdN | Ag3N | CdN | In | Sn | Sb | Te | I | Xe | ||
| Cs3N | Ba3N2 | Hf3N4 | TaN | WN | Re | Os | Ir | Pt | Au | Hg3N2 | TlN | Pb | BiN | Po | At | Rn | |||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La | CeN | Pr | Nd | Pm | Sm | Eu | GdN | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||||
| Ac | Th | Pa | UN | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
- Articles with changed ChemSpider identifier
- ECHA InfoCard ID from Wikidata
- Articles with changed InChI identifier
- Articles containing unverified chemical infoboxes
- Chembox image size set
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- Nitrides
- Zirconium(III) compounds
- Superhard materials
- Refractory materials
- Rock salt crystal structure